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WATER GREMLIN PUBLIC HEALTH ASSESSMENT: PUBLIC COMMENT DRAFT <br />uncertainty factor of 1,000) based on fat accumulation in liver cells (ATSDR, 1996). The unpublished <br />subchro.nic rodent inhalation.study (l7u.Pont,.1998). did not.show any effects thought be to related to <br />exposure to t-DCE, even at doses of 15,800,000 pem3. <br />In their 2010 toxicological review, EPA determined there was enough information to derive a safe <br />amountfor oral exposure tot-DCE. A subchronic.drinking water study:shewing immune suppression in <br />rodents (5hopp et al., 1985) was used to derive an amount of t-DCE.that pep pie could.safely consume <br />over a lifetime (0.02 milligram/kilogram-day). EPA applied an uncertainty factor of 3,0.00 to account for <br />differe bees between animals and humans, variability among humans, use. of a subchronic study, and a <br />lack of additional studies. In January; 2019,. MDH.used .this oral dose to derive a: chronic air guidance <br />value, by converting the oral exposure to inhalation exposure to arrive atthe 70 ug/m3 site -specific RAA. <br />fort=DCE use at Water Gremlin. <br />MPCA Air Modeling <br />As noted earlier, air quality dispersion.model! ng uses computer simulation to predict pollutant <br />concentrations at d iff event: locations.and distances from a source.. MPCA. uses the AERMOD dispersion <br />model, developed and recommended by the U.S. EPA,. to estimate the levels of air pollutants emitted <br />from sou rces,. M PCA conducted air modeling of proposed Water Gremlin t-DCE emissions to back - <br />calculate an annu.a.l emission rate that. would not result in long-term exceedances of the t-DCE inhalation <br />RAA that MDH developed in January 2019. According to the MPCA's mode Iing,.92 tons of t-DCE could be <br />emitted i.n:a Year without exceeding an annual average concentration of 70 µ9/m3 in air outs ide.of the <br />property, <br />Restart of Coating. Operations — March. 2019 <br />Water Gremlin resumed coating operations using€-DCE in place of TCE;. on March 1, 2019 after.MPCA <br />and Water Gremlin signed. a settlement agreement to resolve the company's a1r.quality violations. The <br />agreement limited Water Grem1in's total VOC emissions to 90 to.ns.per year, calculated as.a 12�month <br />rolling: sum, using a mass balance calculation that assumed all t-DCE used 1n operations was emitted to <br />air, except any accounted for as liquid: waste leaving the facility, Based on the air modeling described <br />above; this 90-ton-per-year limit prevents the annual average t-DCE levels from exceeding the. RAA of 70 <br />µg/m3 in any locations where people -live. <br />On August22, 2019, MPCA ordered Water Grerrrilin to suspend the operation of the coating lines <br />because.t-DCE was:found in the soil vapor beneath the.company's production facility building (see <br />section V: Remedial Investigation and Interpretation parts.C. and.D. for more about soil vapor). because <br />of this suspension, t-DCE was only used for -slightly under six months in 2019. The coating lines.remained <br />:shut down until January 21, 2020.. <br />Use of the. coating lines was. phased back in slowly after the suspension, and some lines transitioned to a <br />water -based coating: As a result, less t-DCE was used. in 2020 each month (through March) compared to <br />monthly active coating operations in 2019: The one-year period of t-DCE use (from March 2019- March <br />2020) totaled 60tons. The 12-month rolling sum for emissions decreased in 2020.and fluctuates due to <br />the varied amount of t-DCE used. Additional information: and.a chart.ofthe t-DCE emissions. as :a rolling <br />sum is available on MPCA's website at Water Gremlin air monitoring (www.oca.state.mn.us/airLwatee- <br />gremlin -air -monitoring). <br />16 <br />