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Ion exchange resins are cla-sified as cation or anion <br />exchangers. Both types are produced from the same basic <br />organic polymers. The chemical behavior of the resin is <br />determined by the particular ionizable group attached to the <br />resin. The following is a list of five resin types that may be <br />used by the Facility for metals along with the important <br />characteristics of each. <br />1. Strong Acid Cation •- The important characteristics of this <br />resin type are: The exchange capacity is not affected by <br />the pH of the solution, it is tht least expensive resin, <br />it is the most durable and its selectivity is low so it <br />may pick up hardness in the water. <br />2. Weak Acid Cation - Important characteristics are: The <br />exchange capacity is reduced at a solution pH below 6, it <br />will tend not to pick up water hardness because the <br />selectivity for heavy metal is higher and it is a more <br />expensive resin than the strong acid but a smaller amount <br />of reagents are needed to reverse the reaction and <br />regenerate the resin. <br />3. Strong Base Anion - Important characteristics are: The <br />exchange capacity is unaffected by solution pH, it is <br />generally more expensive than the cation resins, it has a <br />shorter functional life span than cation resins and the <br />resin can be fouled by organics in the solution. <br />4. Weak Base Anion - Important characteristics are: The <br />exchange capacity is reduced above a solution pH of 7, <br />the resin cost is the same as the strong base anion, and <br />less reagent is necessary for resin regeneration than for <br />the strong base anion resin. <br />5. Heavy Metal Chelating Resins - Important characteristics <br />are: It has a higher selectivity for heavy metals than <br />does the weak acid cation resin so it can separate heavy <br />metals from high levels of water hardness in the <br />solution, reduced amounts of reagent are required for <br />regeneration, it is the most expensive resin type, and <br />removal of heavy metals is effective above a solution pH <br />of 4. <br />The ion exchange resins are housed in a canister which is <br />attached to a drain pipe in the rinse tank (see Figure 2). The <br />rinse solution flows through the canister, the metal is removed <br />allowing the exiting water to flow to the sewer. When the <br />exchange capacity of the canister (containing the resins) is <br />reached, it is replaced by a fresh one. Saturated canisters <br />are transported to the Facility and regenerated. Regeneration <br />is accomplished by flushing the resins with a concentrated acid <br />or base solution, depending on the resin type, which effec <br />tively reverses the exchange reaction. <br />A-3 <br />